Читать онлайн

The possibility of synthesising ion-substituted forms of hydrated silver antimonates Ag2γH2-2γSb2O6·2H2O has been studied. For the synthesis, the method of mechanochemical activation of the components of an inorganic mixture consisting of polyantimonic acid (PAA) with H2Sb2O6·2H2O composition and silver nitrate with the concentration range (γ) from 0.0 to 1.0 has been applied. The results of studies of the phase composition of the synthesized compounds and their structural features are presented. Using the Rietveld method, the parameters of the crystal lattice of PAA hydrated ionsubstituted silver forms with a pyrochlore-type structure have been refined. The model for the occupation of metal ions by crystallographic positions has been proposed: the framework of the structure of the compounds is formed by 16c- and 48f -positions, in which Sb5+ and O2- are statistically located; hydrated oxonium ions (H3O+) and silver ions occupy 16d- and 8b-positions respectively. It has been shown that the synthesis of silver forms of PAA is preferably carried out by the mechanochemical synthesis, which results in the complete substitution of proton groups by silver ions in the structure of the compounds.

Ключевые фразы: polyantimonic acid, mechanochemical synthesis, hydrated ion-substituted forms, pyrochlore-type structure, ion-exchange properties
Автор (ы): ЯРОШЕНКО ФЕДОР АЛЕКСАНДРОВИЧ
Соавтор (ы): Бурмистров Владимир Александрович, СИЛОВА А. Е., Лупицкая Юлия Александровна, Филоненко Елена Михайловна, Тимушков Пётр Викторович, Ульянов Максим Николаевич, Саунина Светлана Ивановна
Журнал: ЧЕЛЯБИНСКИЙ ФИЗИКО-МАТЕМАТИЧЕСКИЙ ЖУРНАЛ

Предпросмотр статьи

Идентификаторы и классификаторы

УДК
538.911. Кристаллические, квазирешеточные и другие структуры
538.956. диэлектрические
543.442.3. Ренгеноструктурный анализ
543.573. Методы, связанные с изменением веса. Термогравиметрия
546.865-31. Окись сурьмы Sb2O5
Для цитирования:
ЯРОШЕНКО Ф. А., БУРМИСТРОВ В. А., СИЛОВА А. Е., ЛУПИЦКАЯ Ю. А., ФИЛОНЕНКО Е. М., ТИМУШКОВ П. В., УЛЬЯНОВ М. Н., САУНИНА С. И. MECHANOCHEMICAL SYNTHESIS OF ION-EXCHANGE SILVER FORMS OF POLYANTIMONIC ACID // ЧЕЛЯБИНСКИЙ ФИЗИКО-МАТЕМАТИЧЕСКИЙ ЖУРНАЛ. 2023. Т. 8 № 4
Текстовый фрагмент статьи
Моя история просмотров (10)